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- W2014983514 abstract "Abstract Photocatalytic oxidation of iodide ions and hydrogen evolution proceeded on Pt-loaded titanium dioxide particles in aqueous solutions. The reaction rate levelled off as the concentration of tri-iodide ions increased. This was due to the reduction of tri-iodide ion into iodide ion on the photocatalyst. This process is the back reaction of the energy storing photocatalytic reaction. By introducing an oil phase on the aqueous solution the back reaction was retarded, because part of the tri-iodide ions were transported to the oil phase. The back reaction was much eliminated when durohydroquinone was added to the oil phase. In this case, tri-iodide ions in aqueous solution was scavenged as the result of the redox reaction between tri-iodide ion and durohydroquinone, leading to the prevention of the back reaction. This system is comparable to the functions of photosystem I and plastoquinone in the thylakoid membrane of green plants." @default.
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- W2014983514 date "1997-01-15" @default.
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- W2014983514 title "Forwarding reversible photocatalytic reactions on semiconductor particles using an oil/water boundary" @default.
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