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- W2014985941 abstract "– The circular dichroism of some non-conjugated unsaturated carbonyl compounds, which are conformationally mobile, has been measured at +20° and at about −178°. Specifically for the steroidal compounds 1 and 2 and the monocyclic aldehyde 14, their substituted analogs 4–6, 9–11, and 15–19, respectively, as well as for the aliphatic ketone 21 the CD. temperature gradients are interpreted in terms of the preferred conformations. In the case of the β,γ-unsaturated aldehydes 1 and 14, a correlation of these results with the photolytic decarbonylation from the excited singlet states is discussed." @default.
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- W2014985941 title "Temperaturverhalten des Circulardichroismus und Konformationsanalyse einiger nichtkonjungierter ungesättigter Oxoverbindungen, und auf dem Steroid-Symposium in Mailand, Mai 1966" @default.
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