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- W2014986008 abstract "The roles of hydrophobic ionizable side chains in amphiphilic copolymer gels consisting of 12-acryloyloxydodecanoic acid (ADA, hydrophobic) and acrylic acid (AA, hydrophilic) (ADA/AA) have been investigated by small-angle neutron scattering (SANS). The equilibrium swelling ratio and the structure factor of copolymer gels were obtained as a function of the solvent composition of two mixed solvent systems consisting of water and organic solvents. Propionic acid and 1-propanol were chosen because these solvents have similar values of log P, where P is the partition equilibrium coefficient with respect to octanol/water. This choice made it possible to suppress hydrophobicity effects and to illuminate hydrogen-bonding effects. The ADA/AA gels exhibited different swelling behaviors and disorganization processes of organized structures depending on the kind of mixed solvents in the concentration range of the organic component from x = 2−15 mol %, where x is the mol % of organic solvent in water. SANS results ind..." @default.
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- W2014986008 date "2002-05-25" @default.
- W2014986008 modified "2023-10-18" @default.
- W2014986008 title "Small-Angle Neutron Scattering Study on Selective Solvation of Poly(12-acryloyloxydodecanoic acid-co-acrylic acid) Gels in Mixed Solvents" @default.
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- W2014986008 doi "https://doi.org/10.1021/la011853n" @default.
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