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- W2015013911 abstract "Intrinsic viscosities of dextrans of known branching ratio were measured in water formamide, and in a water-methanol mixture at two temperatures. Weight-average molecular weights (sedimentation equilibrium) ranged from 1.1 × 104 to 1.7 × 106. A model for the hydrolyzed dextran molecule was assumed. Using the methods of Zimm and Stockmayer, the g factor calculated from this model was compared with the g factor obtained from the intrinsic viscosity-molecular weight data through the use of the Flory-Fox theory (g = ratio of squares of radii of gyration of branched to unbranched polymer). The calculated branch lengths required to make consistent the g factors obtained by two different routes were of the same order of magnitude as those found by classical organic chemical methods for other dextran preparations. The intrinsic viscosity-molecular weight relation at 25°C. in water for linear dextran was predicted from the data. It is suggested that investigations of branched polymers of known constitution be carried out by these methods." @default.
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- W2015013911 date "1953-02-01" @default.
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- W2015013911 title "Intrinsic viscosity-molecular weight relationships for dextran" @default.
- W2015013911 doi "https://doi.org/10.1002/pol.1953.120100211" @default.
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