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- W2015016840 abstract "The first zinc containing pyroborates Ni 1,5 Zn 0,5 (B 2 O 5 ) (A ) and Co 1,5 Zn 0,5 (B 2 O 5 ) (B) were prepared by using a B 2 O 3 flux technique. Single crystals were investigated by X-ray diffraction and showed triclinic symmetry, space group C i 1 -P1̅. The structures are isotypic to Co 2 (B 2 O 5 ) with the lattice parameters (A ) a = 331.28(6), b = 613.87(11), c = 922.2(2), α = 104.067(11) °, β = 90.672(13) °, γ = 92.413(12) ° and (B) a = 315.89(2), b = 612.84(6), c = 927.72(6), α = 104.103(7) °, β = 91.020(6) °, γ = 92.540(7) °, Z = 2. All metal point positions show an octahedral oxygen coordination and a partly statistical distribution of Zn 2+ and Ni 2+ or Co 2+ , respectively. Isolated nearly planar B 2 O 5 units connect ribbons consisting of edge sharing metal octahedra." @default.
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- W2015016840 date "1995-10-01" @default.
- W2015016840 modified "2023-10-11" @default.
- W2015016840 title "Synthese und Kristallstruktur der ersten zinkhaltigen Pyroborate Ni<sub>1,5</sub>Zn<sub>0,5</sub>(B<sub>2</sub>O<sub>5</sub>) und Co<sub>1,5</sub>Zn<sub>0,5</sub>(B<sub>2</sub>O<sub>5</sub>) / Synthesis and Crystal Structure of the First Zinc Containing Pyroborates Ni<sub>1,5</sub>Zn<sub>0,5</sub>(B<sub>2</sub>O<sub>5</sub>) and Co<sub>1,5</sub>Zn<sub>0,5</sub>(B<sub>2</sub>O<sub>5</sub>)" @default.
- W2015016840 doi "https://doi.org/10.1515/znb-1995-1003" @default.
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