FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2015017063> ?p ?o ?g. }

• W2015017063 endingPage "11575" @default.
• W2015017063 startingPage "11567" @default.
• W2015017063 abstract "Magic-angle spinning (MAS) NMR spectroscopy is used to study the local structure and spin delocalisation in Prussian blue analogues (PBAs). We selected two common archetypes of PBAs (A(I)M(II)[M(III)(CN)(6)]·xH(2)O and M(II)(3)[M(III)(CN)(6)](2)·xH(2)O, in which A(I) is an alkali ion, and M(II) and M(III) are transition-metal ions) that exhibit similar cubic frameworks but different microscopic structures. Whereas the first type of PBA contains interstitial alkali ions and does not exhibit any [M(III)(CN)(6)](3-) vacancies, the second type of PBA exhibits [M(III)(CN)(6)](3-) vacancies, but does not contain inserted alkali ions. In this study, we selected Cd(II) as a divalent metal in order to use the (113)Cd nuclei (I=1/2) as a probe of the local structure. Here, we present a complete MAS NMR study on two series of PBAs of the formulas Cd(II)(3)[Fe(III)(x)Co(III)(1-x)(CN)(6)](2)·15H(2)O with x=0 (1), 0.25 (2), 0.5 (3), 0.75 (4) and 1 (5), and CsCd(II)[Fe(III)(x)Co(III)(1-x)(CN)(6)]·0.5H(2)O with x=0 (6), 0.25 (7), 0.5 (8), 0.75 (9) and 1 (10). Interestingly, the presence of Fe(III) magnetic centres in the vicinity of the cadmium sites has a magnifying-glass effect on the NMR spectrum: it induces a striking signal spread such that the resolution is notably improved compared to that achieved for the diamagnetic PBAs. By doping the sample with varying amounts of diamagnetic Co(III) and comparing the NMR spectra of both types of PBAs, we have been able to give a view of the structure which is complementary to that usually obtained from X-ray diffraction studies. In particular, this study has shown that the vacancies are not randomly distributed in the mesoporous PBAs. Moreover the cadmium chemical shift, which is a measure of the hyperfine coupling, allows the estimation of the spin density on the cadmium nucleus, and consequently, the elucidation of the spin delocalisation mechanism in these compounds along with its dependency on structural parameters." @default.
• W2015017063 created "2016-06-24" @default.
• W2015017063 creator A5023990780 @default.
• W2015017063 creator A5028912390 @default.
• W2015017063 creator A5059092642 @default.
• W2015017063 creator A5086242934 @default.
• W2015017063 date "2011-08-31" @default.
• W2015017063 modified "2023-09-24" @default.
• W2015017063 title "Probing Spin Density and Local Structure in the Prussian Blue Analogues CsCd[Fe/Co(CN)6]⋅0.5 H2O and Cd3[Fe/Co(CN)6]2⋅15 H2O with Solid-State MAS NMR Spectroscopy" @default.
• W2015017063 cites W1969621897 @default.
• W2015017063 cites W1972581004 @default.
• W2015017063 cites W1981786213 @default.
• W2015017063 cites W1987567813 @default.
• W2015017063 cites W1999217231 @default.
• W2015017063 cites W2000638229 @default.
• W2015017063 cites W2001893199 @default.
• W2015017063 cites W2009773637 @default.
• W2015017063 cites W2017044807 @default.
• W2015017063 cites W2018889291 @default.
• W2015017063 cites W2024214423 @default.
• W2015017063 cites W2024625434 @default.
• W2015017063 cites W2024944083 @default.
• W2015017063 cites W2027660170 @default.
• W2015017063 cites W2027922955 @default.
• W2015017063 cites W2030446652 @default.
• W2015017063 cites W2030463075 @default.
• W2015017063 cites W2038787418 @default.
• W2015017063 cites W2040650475 @default.
• W2015017063 cites W2042290103 @default.
• W2015017063 cites W2046471185 @default.
• W2015017063 cites W2053079998 @default.
• W2015017063 cites W2056182336 @default.
• W2015017063 cites W2058197189 @default.
• W2015017063 cites W2064601914 @default.
• W2015017063 cites W2067550505 @default.
• W2015017063 cites W2080334952 @default.
• W2015017063 cites W2087896221 @default.
• W2015017063 cites W2093178916 @default.
• W2015017063 cites W2097148301 @default.
• W2015017063 cites W2102290782 @default.
• W2015017063 cites W2112875771 @default.
• W2015017063 cites W2114365222 @default.
• W2015017063 cites W2125508205 @default.
• W2015017063 cites W2138277328 @default.
• W2015017063 cites W2144122582 @default.
• W2015017063 cites W2146261838 @default.
• W2015017063 cites W2163623272 @default.
• W2015017063 cites W2169262284 @default.
• W2015017063 cites W2326133559 @default.
• W2015017063 cites W2949608607 @default.
• W2015017063 cites W4205292835 @default.
• W2015017063 cites W4212971472 @default.
• W2015017063 cites W4231654171 @default.
• W2015017063 cites W4232071210 @default.
• W2015017063 cites W4232578807 @default.
• W2015017063 cites W4249230963 @default.
• W2015017063 cites W4252179744 @default.
• W2015017063 doi "https://doi.org/10.1002/chem.201100778" @default.
• W2015017063 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21882267" @default.
• W2015017063 hasPublicationYear "2011" @default.
• W2015017063 type Work @default.
• W2015017063 sameAs 2015017063 @default.
• W2015017063 citedByCount "22" @default.
• W2015017063 countsByYear W20150170632013 @default.
• W2015017063 countsByYear W20150170632014 @default.
• W2015017063 countsByYear W20150170632015 @default.
• W2015017063 countsByYear W20150170632016 @default.
• W2015017063 countsByYear W20150170632017 @default.
• W2015017063 countsByYear W20150170632019 @default.
• W2015017063 countsByYear W20150170632021 @default.
• W2015017063 countsByYear W20150170632022 @default.
• W2015017063 countsByYear W20150170632023 @default.
• W2015017063 crossrefType "journal-article" @default.
• W2015017063 hasAuthorship W2015017063A5023990780 @default.
• W2015017063 hasAuthorship W2015017063A5028912390 @default.
• W2015017063 hasAuthorship W2015017063A5059092642 @default.
• W2015017063 hasAuthorship W2015017063A5086242934 @default.
• W2015017063 hasConcept C145148216 @default.
• W2015017063 hasConcept C147789679 @default.
• W2015017063 hasConcept C17525397 @default.
• W2015017063 hasConcept C178790620 @default.
• W2015017063 hasConcept C185592680 @default.
• W2015017063 hasConcept C198091228 @default.
• W2015017063 hasConcept C2779064266 @default.
• W2015017063 hasConcept C52859227 @default.
• W2015017063 hasConcept C66974803 @default.
• W2015017063 hasConcept C71240020 @default.
• W2015017063 hasConcept C8010536 @default.
• W2015017063 hasConcept C84935128 @default.
• W2015017063 hasConceptScore W2015017063C145148216 @default.
• W2015017063 hasConceptScore W2015017063C147789679 @default.
• W2015017063 hasConceptScore W2015017063C17525397 @default.
• W2015017063 hasConceptScore W2015017063C178790620 @default.
• W2015017063 hasConceptScore W2015017063C185592680 @default.
• W2015017063 hasConceptScore W2015017063C198091228 @default.
• W2015017063 hasConceptScore W2015017063C2779064266 @default.
• W2015017063 hasConceptScore W2015017063C52859227 @default.
• W2015017063 hasConceptScore W2015017063C66974803 @default.

• next