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- W2015019838 abstract "Platinum catalyst thin films prepared by PtO2 decomposition are tentatively characterized by the transition between two stationary reaction states both at constant temperature and constant CO partial pressure. It is demonstrated that at constant temperature, the measurements must be made in the sense of decreasing CO concentration because of reactant diffusion and heat dissipation. Following the model of R. Dagonnier, M. Dumont, and J. Nuyts (J. Catal.66, 130 (1980)), a sum of activation energies corresponding to the surface reaction and the dissociative oxygen adsorption was determined. This sum of activation energies and the ordinate axis intercepts of the Arrhenius plot presented are found to change with ageing of the samples." @default.
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- W2015019838 date "1984-04-01" @default.
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- W2015019838 title "Oxidation of carbon monoxide on thin film catalysts: Characterization by a critical temperature measurement" @default.
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- W2015019838 doi "https://doi.org/10.1016/0021-9517(84)90382-8" @default.
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