Matches in SemOpenAlex for { <https://semopenalex.org/work/W2015052016> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W2015052016 endingPage "1351" @default.
- W2015052016 startingPage "1346" @default.
- W2015052016 abstract "The hydrothermal reaction of Np(IV) or Pu(IV) with KIO4 and CsCl at 180°C for 1 day results in the formation of NpO2(IO3)2·0.5KCl·3.25H2O (1) or PuO2(IO3)2·0.5KCl·2.5H2O (2). The neutral layers in compounds 1 and 2 are isostructural with NpO2(IO3)2·H2O and PuO2(IO3)2·H2O, respectively. The Np and Pu centers are found in distorted pentagonal bipyramidal [AnO7] environments that are formed from the ligation of NpO22+ or PuO22+ cations by iodate anions. There are two crystallographically unique pyramidal iodate anions in 1 and 2. One of these anions utilizes all three oxygen atoms to simultaneously bridge three neptunyl or plutonyl units. The second anion only bridges two actinyl units and has a terminal oxo atom. The bridging of the actinyl cations by iodate anions creates neutral ∞2[AnO2(IO3)3] (An=Np, Pu) sheets that are separated by K+ cations, Cl− anions, and water molecules. Crystallographic data (203 K, MoKα, λ=0.71073): 1, monoclinic, space group C2/c,a=21.537(5) Å, b=11.670(3) Å, c=7.315(2) Å, β=93.033(4)°, Z=4, R(F)=5.43% for 136 parameters with 1309 reflections with I>2σ(I); 2, monoclinic, space group C2/c, a=21.570(4) Å, b=11.656(2) Å, c=7.348(2) Å, β=94.00(3), Z=4, R(F)=4.92% for 148 parameters with 1317 reflections with I>2σ(I)." @default.
- W2015052016 created "2016-06-24" @default.
- W2015052016 creator A5024436206 @default.
- W2015052016 creator A5033721117 @default.
- W2015052016 creator A5051810231 @default.
- W2015052016 creator A5073400356 @default.
- W2015052016 date "2004-04-01" @default.
- W2015052016 modified "2023-10-17" @default.
- W2015052016 title "Intercalation of KCl into layered neptunyl and plutonyl iodates" @default.
- W2015052016 cites W1977888787 @default.
- W2015052016 cites W1985893512 @default.
- W2015052016 cites W2015176563 @default.
- W2015052016 cites W2016329981 @default.
- W2015052016 cites W2018432441 @default.
- W2015052016 cites W2052225712 @default.
- W2015052016 cites W2059658481 @default.
- W2015052016 cites W2063649794 @default.
- W2015052016 cites W2068088378 @default.
- W2015052016 cites W2070413572 @default.
- W2015052016 cites W2074019256 @default.
- W2015052016 cites W2101741054 @default.
- W2015052016 cites W2133330879 @default.
- W2015052016 cites W2165184888 @default.
- W2015052016 cites W2949670848 @default.
- W2015052016 cites W2950848718 @default.
- W2015052016 cites W2950961884 @default.
- W2015052016 cites W2953069506 @default.
- W2015052016 doi "https://doi.org/10.1016/j.jssc.2003.11.011" @default.
- W2015052016 hasPublicationYear "2004" @default.
- W2015052016 type Work @default.
- W2015052016 sameAs 2015052016 @default.
- W2015052016 citedByCount "19" @default.
- W2015052016 countsByYear W20150520162015 @default.
- W2015052016 countsByYear W20150520162017 @default.
- W2015052016 countsByYear W20150520162020 @default.
- W2015052016 countsByYear W20150520162021 @default.
- W2015052016 countsByYear W20150520162023 @default.
- W2015052016 crossrefType "journal-article" @default.
- W2015052016 hasAuthorship W2015052016A5024436206 @default.
- W2015052016 hasAuthorship W2015052016A5033721117 @default.
- W2015052016 hasAuthorship W2015052016A5051810231 @default.
- W2015052016 hasAuthorship W2015052016A5073400356 @default.
- W2015052016 hasConcept C115624301 @default.
- W2015052016 hasConcept C137824038 @default.
- W2015052016 hasConcept C145148216 @default.
- W2015052016 hasConcept C158842870 @default.
- W2015052016 hasConcept C178790620 @default.
- W2015052016 hasConcept C179104552 @default.
- W2015052016 hasConcept C185592680 @default.
- W2015052016 hasConcept C205188671 @default.
- W2015052016 hasConcept C2778870691 @default.
- W2015052016 hasConcept C2780284529 @default.
- W2015052016 hasConcept C32909587 @default.
- W2015052016 hasConcept C61276311 @default.
- W2015052016 hasConcept C7167053 @default.
- W2015052016 hasConcept C8010536 @default.
- W2015052016 hasConceptScore W2015052016C115624301 @default.
- W2015052016 hasConceptScore W2015052016C137824038 @default.
- W2015052016 hasConceptScore W2015052016C145148216 @default.
- W2015052016 hasConceptScore W2015052016C158842870 @default.
- W2015052016 hasConceptScore W2015052016C178790620 @default.
- W2015052016 hasConceptScore W2015052016C179104552 @default.
- W2015052016 hasConceptScore W2015052016C185592680 @default.
- W2015052016 hasConceptScore W2015052016C205188671 @default.
- W2015052016 hasConceptScore W2015052016C2778870691 @default.
- W2015052016 hasConceptScore W2015052016C2780284529 @default.
- W2015052016 hasConceptScore W2015052016C32909587 @default.
- W2015052016 hasConceptScore W2015052016C61276311 @default.
- W2015052016 hasConceptScore W2015052016C7167053 @default.
- W2015052016 hasConceptScore W2015052016C8010536 @default.
- W2015052016 hasIssue "4-5" @default.
- W2015052016 hasLocation W20150520161 @default.
- W2015052016 hasOpenAccess W2015052016 @default.
- W2015052016 hasPrimaryLocation W20150520161 @default.
- W2015052016 hasRelatedWork W1974006672 @default.
- W2015052016 hasRelatedWork W2012345717 @default.
- W2015052016 hasRelatedWork W2015114063 @default.
- W2015052016 hasRelatedWork W2034215322 @default.
- W2015052016 hasRelatedWork W2057834499 @default.
- W2015052016 hasRelatedWork W2084577535 @default.
- W2015052016 hasRelatedWork W2360206195 @default.
- W2015052016 hasRelatedWork W2378154857 @default.
- W2015052016 hasRelatedWork W865370080 @default.
- W2015052016 hasRelatedWork W895751983 @default.
- W2015052016 hasVolume "177" @default.
- W2015052016 isParatext "false" @default.
- W2015052016 isRetracted "false" @default.
- W2015052016 magId "2015052016" @default.
- W2015052016 workType "article" @default.