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- W2015079420 abstract "O-(Glycyl-L-valyl-D-leucyl-L-alanyl-L-valyl)-D- and L-3-hydroxydodecanoic acids (D- and L-isoisariic acids) have been synthesised and their cyclisation has been studied. D-Isoisariic acid was converted through its acid chloride into a cyclopeptolide indistinguishable from isariin, a metabolite of Isaria cretacea. High pressure liquid chromatography was necessary for the isolation of the product from the reaction mixture and facilitated comparison with the natural material. Attempts to cyclise D-isoisariic acid by other methods were unsuccessful." @default.
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- W2015079420 date "1974-01-01" @default.
- W2015079420 modified "2023-10-14" @default.
- W2015079420 title "Polypeptides. Part XXV. Synthesis of isariin" @default.
- W2015079420 doi "https://doi.org/10.1039/p19740000802" @default.
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