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- W2015081569 abstract "Carbamoyl radicals were generated from oxime oxalate amides, and the kinetics of their 4-exo cyclizations onto C=C and C=NO bonds, leading to beta-lactam-containing species, were studied by EPR spectroscopy. DFT computations with model carbamoyl radicals predicted 4-exo ring closures onto C=NO bonds to be facile, especially when tert-butyl substituents were present. The reverse ring-opening reactions were predicted to have much higher activation energies. Experimental evidence also favored slow reverse ring opening." @default.
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- W2015081569 date "2004-12-13" @default.
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- W2015081569 title "Kinetic and Theoretical Study of 4-<i>e</i><i>xo</i> Ring Closures of Carbamoyl Radicals onto CC and CN Bonds" @default.
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- W2015081569 doi "https://doi.org/10.1021/ol047716+" @default.
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