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• W2015091288 startingPage "33" @default.
• W2015091288 abstract "The (4-NO2ImH)+ salt of the [RuCl4(5-NO2Im)2]− anion was obtained by reacting 4-nitroimidazole (4-NO2Im) with activated RuCl3 in aqueous HCl solution. Crystallographic work on the corresponding [P(C6H5)4][RuCl4(5-NO2Im)2] compound (P2/c, a=7.896, b=7.823, c=27.027 Å, β=100.33°, Z=2, R=0.054) revealed a trans-octahedral coordination about the metal and nitroimidazole binding as the 5-nitro tautomer. The 1H NMR signals of the anion are broad and considerably displaced upfield by the paramagnetic Ru(III) centre, but they could be used to follow the solvolysis. One Cl− ligand was displaced by a solvent molecule over a period of days in D2O and in CD3OD, but higher solvolysis products were not observed. N6,N6-Dimethyladenine (DMAD) failed to react with [RuCl4(5-NO2Im)2]− in D2O and did not perturb the normal aquation process. In CD3OD, a 1:1 complex [RuCl3(DMAD)(5-NO2Im)2] appeared slowly in a fresh solution, but much faster when DMAD was added to an aged solution, suggesting that the monosolvent species [RuCl3(CD3OD)(5-NO2Im)2] is actually undergoing substitution. The reaction of RuCl3 with 2-methyl-4(5)-nitroimidazole gave a mixture of at least four unidentified species which could not be separated, showing that the 2-methyl group plays a crucial role in the reactivity in these systems." @default.
• W2015091288 created "2016-06-24" @default.
• W2015091288 creator A5010237017 @default.
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• W2015091288 date "1995-05-01" @default.
• W2015091288 modified "2023-10-07" @default.
• W2015091288 title "Synthesis of the tetrachlorobis(5-nitroimidazole)ruthenium(III) anion and solution chemistry in water and methanol" @default.
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• W2015091288 doi "https://doi.org/10.1016/0020-1693(94)04400-p" @default.
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