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- W2015092421 abstract "Abstract Polyamide acid solutions (polyimide precursors) doped with either anhydrous cobalt(II) chloride or tin(II) chloride dihydrate and cast on glass plates yield highly anisotropic structures having distinct air-side, glass-side and volume mode (bulk) properties. The room temperature d.c. electrical resistivity is considerably decreased relative to the non-doped polyimide for the air-side, but the glass-side and bulk resistivities are only slightly reduced. Charge-time profiles indicate a substantial polymer matrix contribution to both the glass-side and volume mode measurements but a minimal contribution to the air-side properties. At a constant applied field the electrical resistivity for each measurement mode decreases with increasing temperature as expected for semiconductors and insulators. X-ray photoelectron spectroscopy indicates the presence of metal oxide near the air side. Near-surface metal enrichment and metal oxide formation were found to be dependent on processing conditions and in turn critically influenced electrical properties. Electrical, thermal and spectroscopic data obtained on cobalt(II) and tin(II) doped systems are compared and contrasted in order to document these conclusions." @default.
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- W2015092421 date "1988-04-01" @default.
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- W2015092421 title "Comparison of the electrical properties of polyimide films containing surface metal oxide: Cobalt oxide vs. tin oxide" @default.
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