Matches in SemOpenAlex for { <https://semopenalex.org/work/W2015101005> ?p ?o ?g. }
- W2015101005 endingPage "4894" @default.
- W2015101005 startingPage "4888" @default.
- W2015101005 abstract "The Lewis acidity of GaF3, GaF2Cl, GaFCl2, and GaCl3 in acid−base interactions has been studied by taking ammonia as their electron-donating counterpart. We have derived an unoccupied reactive orbital that shows the maximum localization on the Ga atomic center for each species. The orbital is located lower in energy compared to those in the corresponding boron and aluminum halides. In contrast to boron halides, the unoccupied reactive orbital of the acid site tends to be delocalized considerably on the halogens as the fluorines are substituted by chlorines in gallium halides. The trend observed in the effects of fluorine and chlorine on the acidity of the gallium halides is opposite to those found in the boron halides. This cannot be interpreted solely in terms of the electron-accepting strength of the gallium center, but can be understood by including electrostatic interactions and closed-shell repulsion with ammonia in the adducts. The origin of the difference in Lewis acidity of BCl3, AlCl3, and GaCl3 has been clarified." @default.
- W2015101005 created "2016-06-24" @default.
- W2015101005 creator A5007428793 @default.
- W2015101005 creator A5051131902 @default.
- W2015101005 date "2002-08-24" @default.
- W2015101005 modified "2023-10-10" @default.
- W2015101005 title "Lewis Acidity of Gallium Halides" @default.
- W2015101005 cites W1964777481 @default.
- W2015101005 cites W1972738728 @default.
- W2015101005 cites W1977484451 @default.
- W2015101005 cites W1985010001 @default.
- W2015101005 cites W1986606023 @default.
- W2015101005 cites W1991422811 @default.
- W2015101005 cites W1992642533 @default.
- W2015101005 cites W1996337738 @default.
- W2015101005 cites W1997325498 @default.
- W2015101005 cites W1998692389 @default.
- W2015101005 cites W2002906939 @default.
- W2015101005 cites W2004641115 @default.
- W2015101005 cites W2005877813 @default.
- W2015101005 cites W2008708918 @default.
- W2015101005 cites W2011713407 @default.
- W2015101005 cites W2012354329 @default.
- W2015101005 cites W2013498981 @default.
- W2015101005 cites W2014147806 @default.
- W2015101005 cites W2016225661 @default.
- W2015101005 cites W2017616529 @default.
- W2015101005 cites W2020042245 @default.
- W2015101005 cites W2020253399 @default.
- W2015101005 cites W2021780425 @default.
- W2015101005 cites W2023271753 @default.
- W2015101005 cites W2024034581 @default.
- W2015101005 cites W2030387747 @default.
- W2015101005 cites W2031552499 @default.
- W2015101005 cites W2032756923 @default.
- W2015101005 cites W2034429364 @default.
- W2015101005 cites W2034887381 @default.
- W2015101005 cites W2037933611 @default.
- W2015101005 cites W2038767330 @default.
- W2015101005 cites W2039273991 @default.
- W2015101005 cites W2040014948 @default.
- W2015101005 cites W2040457180 @default.
- W2015101005 cites W2043008767 @default.
- W2015101005 cites W2044202126 @default.
- W2015101005 cites W2044871201 @default.
- W2015101005 cites W2045045577 @default.
- W2015101005 cites W2045615339 @default.
- W2015101005 cites W2048364142 @default.
- W2015101005 cites W2051559441 @default.
- W2015101005 cites W2051597846 @default.
- W2015101005 cites W2053684769 @default.
- W2015101005 cites W2058544139 @default.
- W2015101005 cites W2060861092 @default.
- W2015101005 cites W2063565138 @default.
- W2015101005 cites W2068559689 @default.
- W2015101005 cites W2072294305 @default.
- W2015101005 cites W2072748704 @default.
- W2015101005 cites W2077541775 @default.
- W2015101005 cites W2077570176 @default.
- W2015101005 cites W2078409902 @default.
- W2015101005 cites W2079658373 @default.
- W2015101005 cites W2084323144 @default.
- W2015101005 cites W2084364298 @default.
- W2015101005 cites W2093030588 @default.
- W2015101005 cites W2100104156 @default.
- W2015101005 cites W2143981217 @default.
- W2015101005 cites W2148941593 @default.
- W2015101005 cites W2157879889 @default.
- W2015101005 cites W2163560029 @default.
- W2015101005 cites W2312895420 @default.
- W2015101005 cites W2313255320 @default.
- W2015101005 cites W2317425102 @default.
- W2015101005 cites W2322066880 @default.
- W2015101005 cites W2323658865 @default.
- W2015101005 cites W2332910307 @default.
- W2015101005 cites W2335322701 @default.
- W2015101005 cites W2949977006 @default.
- W2015101005 cites W2950087092 @default.
- W2015101005 cites W2950197408 @default.
- W2015101005 cites W2950910355 @default.
- W2015101005 cites W2951746136 @default.
- W2015101005 cites W2951924193 @default.
- W2015101005 cites W3005051657 @default.
- W2015101005 cites W4233998925 @default.
- W2015101005 doi "https://doi.org/10.1021/ic020268m" @default.
- W2015101005 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/12230392" @default.
- W2015101005 hasPublicationYear "2002" @default.
- W2015101005 type Work @default.
- W2015101005 sameAs 2015101005 @default.
- W2015101005 citedByCount "24" @default.
- W2015101005 countsByYear W20151010052012 @default.
- W2015101005 countsByYear W20151010052013 @default.
- W2015101005 countsByYear W20151010052014 @default.
- W2015101005 countsByYear W20151010052016 @default.
- W2015101005 countsByYear W20151010052018 @default.
- W2015101005 countsByYear W20151010052019 @default.
- W2015101005 countsByYear W20151010052020 @default.
- W2015101005 countsByYear W20151010052021 @default.