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- W2015118974 abstract "Acetolysis of 1,6 : 3,4-dianhydro-2-O- p -toluenesulfonyl-β-D-galactopyranose ( I ) gave 3,4-di-O-acetyl-1,6-anhydro-2-O- p -toluenesulfonyl-β-D-glucopyranose ( II ) which was converted with sodium methoxide to 1,6 : 3,4-dianhydro-β-D-altropyranose ( X ). The 1,6-anhydride bond in diacetate II was cleaved with acetic anhydride or hydrogen bromide in acetic acid under formation of a mixture of anomeric tetraacetates of 2-O- p -toluenesulfonyl-D-glucopyranose or the corresponding acetates of α-D-glucopyranosyl bromide XIII and its 6-bromo-6-deoxy derivative XIV ." @default.
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- W2015118974 date "1982-01-01" @default.
- W2015118974 modified "2023-10-09" @default.
- W2015118974 title "Preparation of 1,6:3,4-dianhydro-β-D-altropyranose as starting substance for the synthesis of 3-substituted D-mannose derivatives" @default.
- W2015118974 doi "https://doi.org/10.1135/cccc19822415" @default.
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