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- W2015129145 abstract "In the title compound, poly[[triaqua{μ(4)-2-[4,6-bis(carboxymethylsulfanyl)-1,3,5-triazin-2-ylsulfanyl]acetato}{μ(2)-2-[4,6-bis(carboxymethylsulfanyl)-1,3,5-triazin-2-ylsulfanyl]acetato}barium(II)] monohydrate], {[Ba(C(9)H(8)N(3)O(6)S(3))(2)(H(2)O)(3)]·H(2)O}(n), each Ba(II) atom is nine-coordinated by six O atoms from carboxylate groups of four different 2-[4,6-bis(carboxymethylsulfanyl)-1,3,5-triazin-2-ylsulfanyl]acetate ligands and three O atoms from water molecules. The triazine ligand is partially deprotonated, as verified by intermolecular hydrogen-bonding parameters, and adopts μ(2)-η(1):η(1) and μ(4)-η(1):η(1):η(2) coordination modes to connect the Ba(II) centres, forming a novel double-layered structure. Topological analysis indicates that the whole structure is a novel (4,6)-connected net, considering the ligands and Ba(II) centres as four- and six-connected nodes, respectively." @default.
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- W2015129145 date "2010-10-27" @default.
- W2015129145 modified "2023-10-16" @default.
- W2015129145 title "A novel (4,6)-connected double-layered Ba<sup>II</sup>coordination polymer based on the flexible tricarboxylate ligand 2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfanediyl)]triacetic acid" @default.
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- W2015129145 doi "https://doi.org/10.1107/s0108270110042496" @default.
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