Matches in SemOpenAlex for { <https://semopenalex.org/work/W2015132847> ?p ?o ?g. }
Showing items 1 to 99 of
99
with 100 items per page.
- W2015132847 endingPage "162" @default.
- W2015132847 startingPage "156" @default.
- W2015132847 abstract "The objective of this study was to exploit the advantages of stripping chronopotentiometry (SCP) and stripping chronopotentiometry at scanned deposition potential (SSCP) for trace metal speciation analyses by using thin-film mercury screen-printed electrodes (TMF-SPE). At first, the SCP parameters were optimised for TMF-SPE, in order to reach the complete depletion regime. It has been shown that a stripping current higher than or equal to 10 μA allows this regime to be attained without removing oxygen from the solution. Then, these analytical conditions were used for the construction of SSCP curves for Cd-PDCA and Cd-NTA. When the concentration of free ligand in solution was known, the knowledge of the model describing the SSCP curves in absence and presence of a complex and the use of an effective fitting tool enabled estimating the stability constant and the rate constants for complexation. Further studies with complexes of restricted mobility are however necessary to assess the usefulness of this procedure to also estimate the diffusion coefficient of the complexes. Besides, this study showed that this approach was valid even when ligands were not in excess at the electrode during stripping." @default.
- W2015132847 created "2016-06-24" @default.
- W2015132847 creator A5040954382 @default.
- W2015132847 creator A5048892193 @default.
- W2015132847 creator A5064741632 @default.
- W2015132847 creator A5083558661 @default.
- W2015132847 date "2011-03-01" @default.
- W2015132847 modified "2023-10-15" @default.
- W2015132847 title "Determination of trace metal speciation parameters by using screen-printed electrodes in stripping chronopotentiometry without deaerating" @default.
- W2015132847 cites W1559216609 @default.
- W2015132847 cites W1968213954 @default.
- W2015132847 cites W1970709576 @default.
- W2015132847 cites W1982648012 @default.
- W2015132847 cites W1992634591 @default.
- W2015132847 cites W1995060842 @default.
- W2015132847 cites W2006817645 @default.
- W2015132847 cites W2017037990 @default.
- W2015132847 cites W2036086851 @default.
- W2015132847 cites W2060004353 @default.
- W2015132847 cites W2066305659 @default.
- W2015132847 cites W2067629852 @default.
- W2015132847 cites W2073683338 @default.
- W2015132847 cites W2079985473 @default.
- W2015132847 cites W2084243196 @default.
- W2015132847 cites W2088025259 @default.
- W2015132847 cites W2110981663 @default.
- W2015132847 cites W2142785262 @default.
- W2015132847 cites W2153664109 @default.
- W2015132847 doi "https://doi.org/10.1016/j.aca.2010.12.034" @default.
- W2015132847 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21334480" @default.
- W2015132847 hasPublicationYear "2011" @default.
- W2015132847 type Work @default.
- W2015132847 sameAs 2015132847 @default.
- W2015132847 citedByCount "19" @default.
- W2015132847 countsByYear W20151328472012 @default.
- W2015132847 countsByYear W20151328472013 @default.
- W2015132847 countsByYear W20151328472014 @default.
- W2015132847 countsByYear W20151328472015 @default.
- W2015132847 countsByYear W20151328472016 @default.
- W2015132847 countsByYear W20151328472017 @default.
- W2015132847 countsByYear W20151328472018 @default.
- W2015132847 countsByYear W20151328472019 @default.
- W2015132847 countsByYear W20151328472020 @default.
- W2015132847 countsByYear W20151328472021 @default.
- W2015132847 countsByYear W20151328472022 @default.
- W2015132847 countsByYear W20151328472023 @default.
- W2015132847 crossrefType "journal-article" @default.
- W2015132847 hasAuthorship W2015132847A5040954382 @default.
- W2015132847 hasAuthorship W2015132847A5048892193 @default.
- W2015132847 hasAuthorship W2015132847A5064741632 @default.
- W2015132847 hasAuthorship W2015132847A5083558661 @default.
- W2015132847 hasConcept C113196181 @default.
- W2015132847 hasConcept C147789679 @default.
- W2015132847 hasConcept C159985019 @default.
- W2015132847 hasConcept C17525397 @default.
- W2015132847 hasConcept C178790620 @default.
- W2015132847 hasConcept C185592680 @default.
- W2015132847 hasConcept C192562407 @default.
- W2015132847 hasConcept C41952129 @default.
- W2015132847 hasConcept C43617362 @default.
- W2015132847 hasConcept C52859227 @default.
- W2015132847 hasConcept C544153396 @default.
- W2015132847 hasConcept C81557720 @default.
- W2015132847 hasConceptScore W2015132847C113196181 @default.
- W2015132847 hasConceptScore W2015132847C147789679 @default.
- W2015132847 hasConceptScore W2015132847C159985019 @default.
- W2015132847 hasConceptScore W2015132847C17525397 @default.
- W2015132847 hasConceptScore W2015132847C178790620 @default.
- W2015132847 hasConceptScore W2015132847C185592680 @default.
- W2015132847 hasConceptScore W2015132847C192562407 @default.
- W2015132847 hasConceptScore W2015132847C41952129 @default.
- W2015132847 hasConceptScore W2015132847C43617362 @default.
- W2015132847 hasConceptScore W2015132847C52859227 @default.
- W2015132847 hasConceptScore W2015132847C544153396 @default.
- W2015132847 hasConceptScore W2015132847C81557720 @default.
- W2015132847 hasIssue "2" @default.
- W2015132847 hasLocation W20151328471 @default.
- W2015132847 hasLocation W20151328472 @default.
- W2015132847 hasLocation W20151328473 @default.
- W2015132847 hasLocation W20151328474 @default.
- W2015132847 hasOpenAccess W2015132847 @default.
- W2015132847 hasPrimaryLocation W20151328471 @default.
- W2015132847 hasRelatedWork W1997818827 @default.
- W2015132847 hasRelatedWork W2000275141 @default.
- W2015132847 hasRelatedWork W2015027900 @default.
- W2015132847 hasRelatedWork W2041372633 @default.
- W2015132847 hasRelatedWork W2083486877 @default.
- W2015132847 hasRelatedWork W2123604744 @default.
- W2015132847 hasRelatedWork W2132596775 @default.
- W2015132847 hasRelatedWork W2366708696 @default.
- W2015132847 hasRelatedWork W4239532806 @default.
- W2015132847 hasRelatedWork W4287009610 @default.
- W2015132847 hasVolume "688" @default.
- W2015132847 isParatext "false" @default.
- W2015132847 isRetracted "false" @default.
- W2015132847 magId "2015132847" @default.
- W2015132847 workType "article" @default.