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• W2015134345 abstract "Many phytopathogenic bacteria display lipopolysaccharides (LPS) with the O-chain repeating unit [α-l-Rha-(1→3)-α-l-Rha-(1→3)-α-l-Rha-(1→2)]n. This trisaccharide unit was synthesized and oligomerized to obtain hexa- and nonasaccharides. The deprotected rhamnans were effective in suppressing the hypersensitive response (HR) and in inducing PR-1 gene expression in Arabidopsis thaliana. Conformational analysis of the oligorhamnans by NMR spectroscopy and molecular dynamics calculations revealed that a coiled structure develops with increasing chain length of the oligosaccharide. This is associated with increasing efficacy in HR suppression and PR-1 gene expression. We therefore infer that the coiled structure of phytopathogenic bacteria is a plant-recognizable pathogen-associated molecular pattern (PAMP)." @default.
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• W2015134345 date "2005-02-04" @default.
• W2015134345 modified "2023-10-09" @default.
• W2015134345 title "Structure-Dependent Modulation of a Pathogen Response in Plants by Synthetic O-Antigen Polysaccharides" @default.
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• W2015134345 doi "https://doi.org/10.1021/ja0452166" @default.
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