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- W2015142718 abstract "The addition of a hydrocarbon bridge between the 2- and 2′-positions in biphenyl constrains the twist angle between the two phenyl rings to fairly small limits. It has been found that the biological activity of a series of pyrethroid esters, of hydrocarbon bridged biphenyl-3-ylmethanols and of heterocyclic hydrocarbonbridged biphenyl analogues, changes with the length of the bridge. The optimum activity and the maximum biological activity spectrum were found for the esters of three-carbon bridged alcohols. The relationship of the activity to the twist angle for these bridged esters was compared with the activity and spectrum of a series of biphenyl and heterocyclic biphenyl analogues previously reported. A parallel exists between the two series. The optimum twist angle between the aromatic rings of the alcohols, in both the bridged and free rotating analogues, is around 50°. Pyrethroid esters showing the highest activity were produced from 6, 7-dihydro-5H-dibenzo-[a,c]cyclohepten-4-ylmethanol. The biological activity of a series of pyrethroid esters of this alcohol is also reported." @default.
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- W2015142718 date "1984-10-01" @default.
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- W2015142718 title "Pyrethroid insecticides derived from 2,2′ -bridged biphenyl-3-ylmethanols" @default.
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- W2015142718 doi "https://doi.org/10.1002/ps.2780150513" @default.
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