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- W2015145826 abstract "A model for the tricritical point of the first order chain melting transition in a monomolecular layer of long chain amphiphilic molecules is presented. It is based on the two state model of chain melting where the surface pressure and intramolecular degrees of freedom enter through an effective internal field. Two order parameters are introduced: the degree of the intramolecular isomerization η and the nematic parameter Δ characterizing the anisotropic distribution of the orientation of the molecules on the plane of the interface. A coupling between these two order parameters is sufficient to transform, at a tricritical point, the high temperature second order nematic phase transition on Δ to a first order transition on Δ and η at lower temperature. Based on these results, an alternative allocation of the phases for the two‐dimensional monomolecular system is proposed." @default.
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- W2015145826 date "1981-02-15" @default.
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- W2015145826 title "Model for the tricritical point of the chain‐melting transition in a monomolecular layer of amphiphilic molecules" @default.
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- W2015145826 doi "https://doi.org/10.1063/1.441328" @default.
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