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- W2015152079 abstract "The reductions of TCNQ and TCNE to their anion radicals and dianions at platinum and carbon electrodes in acetonitrile solution have been studied by cyclic voltammetry, using a variety of supporting electrolytes. At sweep rates up to 500 mV s−1 the first reduction waves of both TCNQ and TCNE are reversible, with half-wave potentials independent of supporting electrolyte and electrode material. The half-wave potentials of the second reduction waves, however, are less negative in the presence of LiClO4 or NaClO4 than in the presence of TBAF or TEAP. This is attributed to ion pairing between the dianions and the alkali metal cations. The second reduction wave of TCNQ is reversible up to 500 mV s−1 but the electrode kinetics of the second wave of TCNE are dependent upon electrolyte and electrode material, probably because of variations in the metal-outer Helmholz plane distance or non-adiabaticity." @default.
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- W2015152079 date "1986-12-01" @default.
- W2015152079 modified "2023-09-23" @default.
- W2015152079 title "Electrolyte effects on the cyclic voltammetry of TCNQ and TCNE" @default.
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- W2015152079 doi "https://doi.org/10.1016/0022-0728(86)87021-8" @default.
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