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• W2015155330 abstract "Transient phenomena, namely the incubation period of the reaction and the vibrational relaxation process, are studied for thermal unimolecular reactions of polyatomic molecules. Analytical solutions of the master equation are obtained for idealized models, and the results are compared with computer numerical solutions. It is demonstrated that measurements of incubation times provide a direct access to energy transfer of highly excited molecules. Experimentally observed incubation times in the thermal decomposition of N2O are analyzed." @default.
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• W2015155330 date "1978-12-01" @default.
• W2015155330 modified "2023-09-25" @default.
• W2015155330 title "Theory of transient phenomena in thermal unimolecular reactions" @default.
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• W2015155330 doi "https://doi.org/10.1016/0301-0104(78)85187-8" @default.
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