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- W2015156727 abstract "Reactions of tricarbonyl(η6-triisopropylsilyl(TIPS)benzene)chromium(0) complex 1b with various alkyllithiums proceed regioselectively, giving para-substituted TIPSbenzenes in high yield after oxidation with iodine. Vinyllithiums also react with the TIPSbenzenechromium complex to give para-TIPSstyrenes in good yield. In the reaction with phenyllithium, although the para-substituted product is obtained as a main product, deprotonation of the aryl group of the chromium complex also occurs competitively to afford bisTIPSbiphenyls as a by-product. Alkynyllithium, however, attacks the TIPS group to yield alkynylsilane and TIPSbiphenyl." @default.
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- W2015156727 date "1994-04-01" @default.
- W2015156727 modified "2023-10-12" @default.
- W2015156727 title "Regioselective Alkylation of (<i>η</i><sup>6</sup>-Triisopropylsilylbenzene)chromium(0) Complex with Organolithium Compounds" @default.
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- W2015156727 doi "https://doi.org/10.1246/bcsj.67.1156" @default.
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