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- W2015160911 abstract "Die Oxime des eis-2,6-Diphenyl-1-oxa-und 1-thia-cyclohexanons sowie des cis-2,6-Diphenyl-1-methyl-piperidons werden kernresonanzspektroskopisch untersucht. Auffallend ist in den Spektren dieser Verbindungen die große Differenz zwischen den chemischen Verschiebungen des äquatorialen und des axialen Protons der syn-Methylengruppe. Aus den Spektren der trans-2,6-Diphenyl-1-oxa-und 1-thia-cyclohexanon-(4)-oxime ist zu folgern, daß diese Verbindungen in einer rasch invertierenden Sesselkonformation vorliegen. Stereochemistry of some aryl substituted heterocyclic Ketoximes The 1H-NMR spectra of the cis-2,6-diphenyl 1-oxa- and 1-thia-4-cyclohexanone oximes and of the cis-2,6-diphenyl 1-methyl 4-piperidone oxime have been studied. In the spectra of all these compounds, an important difference is observed between the chemical shifts of the equatorial and the axial proton of the syn-methylene group. From the spectra of the trans-2,6-diphenyl 1-oxa- and 1-thia-4-cyclohexanone oximes a rapidly inverting chair conformation can be concluded for these compounds." @default.
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- W2015160911 date "1970-01-01" @default.
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- W2015160911 title "Zur Stereochemie einiger arylsubstituierter heterocyclischer Ketoxime" @default.
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- W2015160911 doi "https://doi.org/10.1002/ardp.19703030104" @default.
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