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- W2015170915 abstract "The development and commercialisation of the LiFePO4cathode for lithium ion batteries provoked the strong interest to the other members of the olivine-like metallophosphates family LiMPO4 (M = Mn, Fe, Co, Ni). It is well known that lithium extraction from LiFePO4 (triphylite) leads to the formation of the newphase FePO4 (heterosite), which is isostructural to the pristine compound [1]. By the in-situ synchrotron diffraction we studied the structural changes occurring at the delithiation of LiMn0.6Fe0.4PO4 and LiCoPO4. The extraction of lithium fromLiMn0.6Fe0.4PO4 proceeds as a two-step process [2]. The first step (ca. 3.6 V vs. Li/Li) corresponds to the oxidation of iron (Fe/Fe), the second one (ca. 4.1 V vs. Li/Li) to the oxidation ofmanganese (Mn/Mn). In contrast to the mechanism earlier reported for this compound [3], both reactions were revealed to proceed in two-phase manner. A solid solution domain seems to exist in the intermediate state, where Fe/Fe electrochemical reaction ends and Mn/Mn begins. All phases appearing during charging the cell have the same olivine-like structure with different cell parameters. The two step character of lithium extraction for LiCoPO4 was observed also and confirmed by XAS measurements [4, 5]. In in-situ diffraction experiments on LiCoPO4 reveal the formation of lithium-poor olivine-like phase at the earlier stage of charge." @default.
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- W2015170915 date "2006-08-06" @default.
- W2015170915 modified "2023-09-26" @default.
- W2015170915 title "Mechanism of lithium insertion-extraction in metallophosphates with olivine-like structure" @default.
- W2015170915 doi "https://doi.org/10.1107/s0108767306097868" @default.
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