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- W2015174375 abstract "Abstract EPR probed the zincblende ( γ ) to cubic ( α ) AgI structural phase transition in AgI at 423 K through two intrinsic paramagnetic centers: an Ag 2+ -based hole center (signal ‘A’) and an Ag 0 -based conduction electron center (signal ‘B’) associated with AgI nanocrystallites. Sudden drops in intensity ( I PP ), g >, and Δ H PP observed at 423 K for pure AgI nanocrystals. Addition of Cu in AgI increases the thermal stability of the cation sublattice as seen from the increase in the transition temperature from 423 K (undoped AgI) to 453 K. Abrupt jumps in the number of spins (N) and reciprocal susceptibility (1/ χ ) observed at increased phase transition temperatures in Cu-substituted AgI relative to that in undoped AgI reflects progressively strengthened local bonding configuration of γ -AgI structure induced by Cu." @default.
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- W2015174375 date "2006-12-01" @default.
- W2015174375 modified "2023-09-26" @default.
- W2015174375 title "Intrinsic paramagnetic defects probe superionic phase transition in Ag1−xCuxI (x=0, 0.05, 0.15 and 0.50) nanocrystals" @default.
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- W2015174375 doi "https://doi.org/10.1016/j.jpcs.2006.07.017" @default.
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