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- W2015176870 abstract "Samples of ice XII containing varying amounts of high-density amorphous water (HDA) were prepared by pressurizing hexagonal ice up to 1.8 GPa at 77 K, and they were characterized by X-ray diffraction and differential scanning calorimetry (DSC). Only exotherms were observed in the DSC curves on heating at a rate of 10 K min-1 up to the melting point: conversion of HDA to low-density amorphous water (LDA) at 124 K, LDA→cubic ice transition at 166 K, and at 155 K from ice XII to cubic ice. Thus, unlike ice VIII, ice XII converts directly into cubic ice, and not via LDA. The enthalpy of the ice XII→cubic ice transition is −1.27 ± 0.05 kJ mol-1. From comparison with the reported enthalpy value of the ice V→cubic ice transition of −0.915 kJ mol-1 determined at similar temperature (Handa, Y. P.; Klug, D. D.; Whalley, E. Can. J. Chem. 1988, 66, 919), we conclude that ice XII is metastable with respect to ice V in the investigated temperature range." @default.
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- W2015176870 date "2000-12-01" @default.
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- W2015176870 title "Thermal Properties of Metastable Ice XII" @default.
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- W2015176870 doi "https://doi.org/10.1021/jp003151x" @default.
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