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- W2015192928 abstract "We report a systematic study on preparation and morphology control of macroscopically homogeneous hybrid films composed of a block copolymer and a metal salt, where one block interacts with a metal salt by metal-to-ligand coordination. Hybrids were prepared by blending a polystyrene-b-poly(4-vinylpyridine) (PS−P4VP, Mn=37K, ϕs=0.79) block copolymer and iron(III) chloride (FeCl3) with changing the mole fraction of FeCl3. To prevent the rapid cross-linking formation between P4VP and FeCl3, pyridine as a polar solvent with the coordination ability was used at the solvent-casting stage, which turned out to be effective to prepare macroscopically homogeneous films with a large amount of FeCl3. Transmission electron microscopy and small-angle X-ray scattering measurements were carried out to observe the morphology of thermally annealed samples at the nanoscopic scale. It was revealed that simple two-phase nanostructures were observed due to homogeneously mixing of FeCl3 into a P4VP phase up to 0.9 mol equiv of FeCl3 to pyridine units in P4VP. This indicates FeCl3 works as a filler in a P4VP phase just as small homopolymers: domain expansion and morphology transition were observed as the amount of added FeCl3 increases. However, overflow of FeCl3 was observed in the hybrid with an amount of 1.0 mol equiv of FeCl3. This is probably due to the saturation of incorporated FeCl3, indicating that morphology of the present system can be controlled by stoichiometric balance between 4-vinylpyridine units and FeCl3." @default.
- W2015192928 created "2016-06-24" @default.
- W2015192928 creator A5034802573 @default.
- W2015192928 creator A5046785947 @default.
- W2015192928 creator A5053585184 @default.
- W2015192928 creator A5067585416 @default.
- W2015192928 date "2010-05-20" @default.
- W2015192928 modified "2023-10-15" @default.
- W2015192928 title "Preparation and Morphology Control of Block Copolymer/Metal Salt Hybrids via Solvent-Casting by Using a Solvent with Coordination Ability" @default.
- W2015192928 cites W1530128299 @default.
- W2015192928 cites W1965252165 @default.
- W2015192928 cites W1965565894 @default.
- W2015192928 cites W1970871130 @default.
- W2015192928 cites W1977332823 @default.
- W2015192928 cites W1979252816 @default.
- W2015192928 cites W1979975654 @default.
- W2015192928 cites W1981339964 @default.
- W2015192928 cites W1982189923 @default.
- W2015192928 cites W1984195737 @default.
- W2015192928 cites W1986653669 @default.
- W2015192928 cites W1987998686 @default.
- W2015192928 cites W1994512985 @default.
- W2015192928 cites W1999937609 @default.
- W2015192928 cites W2001798443 @default.
- W2015192928 cites W2003988556 @default.
- W2015192928 cites W2004644983 @default.
- W2015192928 cites W2006400881 @default.
- W2015192928 cites W2008342341 @default.
- W2015192928 cites W2009300060 @default.
- W2015192928 cites W2015500489 @default.
- W2015192928 cites W2015784791 @default.
- W2015192928 cites W2015945537 @default.
- W2015192928 cites W2018050944 @default.
- W2015192928 cites W2019088791 @default.
- W2015192928 cites W2019303915 @default.
- W2015192928 cites W2022315549 @default.
- W2015192928 cites W2023444109 @default.
- W2015192928 cites W2026100316 @default.
- W2015192928 cites W2026160404 @default.
- W2015192928 cites W2030980203 @default.
- W2015192928 cites W2034125211 @default.
- W2015192928 cites W2034334653 @default.
- W2015192928 cites W2034416692 @default.
- W2015192928 cites W2034501059 @default.
- W2015192928 cites W2046476225 @default.
- W2015192928 cites W2047722355 @default.
- W2015192928 cites W2048106063 @default.
- W2015192928 cites W2048732500 @default.
- W2015192928 cites W2049108033 @default.
- W2015192928 cites W2050720097 @default.
- W2015192928 cites W2052566608 @default.
- W2015192928 cites W2054368533 @default.
- W2015192928 cites W2057642744 @default.
- W2015192928 cites W2057915912 @default.
- W2015192928 cites W2058636104 @default.
- W2015192928 cites W2058827055 @default.
- W2015192928 cites W2062890738 @default.
- W2015192928 cites W2065230155 @default.
- W2015192928 cites W2066034379 @default.
- W2015192928 cites W2067415778 @default.
- W2015192928 cites W2070577204 @default.
- W2015192928 cites W2071505248 @default.
- W2015192928 cites W2072376459 @default.
- W2015192928 cites W2073777485 @default.
- W2015192928 cites W2075887685 @default.
- W2015192928 cites W2078270919 @default.
- W2015192928 cites W2079079189 @default.
- W2015192928 cites W2079177104 @default.
- W2015192928 cites W2079536149 @default.
- W2015192928 cites W2080137297 @default.
- W2015192928 cites W2080731876 @default.
- W2015192928 cites W2090064426 @default.
- W2015192928 cites W2093640652 @default.
- W2015192928 cites W2095116945 @default.
- W2015192928 cites W2104018884 @default.
- W2015192928 cites W2113246166 @default.
- W2015192928 cites W2117441301 @default.
- W2015192928 cites W2120734910 @default.
- W2015192928 cites W2157072115 @default.
- W2015192928 cites W2161565472 @default.
- W2015192928 cites W2164043498 @default.
- W2015192928 cites W2172949807 @default.
- W2015192928 cites W4230344563 @default.
- W2015192928 cites W4252446124 @default.
- W2015192928 doi "https://doi.org/10.1021/ma1007286" @default.
- W2015192928 hasPublicationYear "2010" @default.
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