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- W2015199265 abstract "Variable-temperature 1H n.m.r. lineshape analysis has been used to determine the kinetics of axial ligand exchange in 1-methylimidazole and 4-t-butylpyridine complexes of benzyl isocyanide(tetraphenylporphyrinato)ruthenium(II). The results are compared with those for other ruthenium(II) porphyrins and for ruthenium(II) complexes of simple amine ligands, and discussed in terms of π bonding and anti-symbiotic effects. The cis effect of tetraphenylporphyrin is much less in ruthenium(II) complexes than in their iron(II) analogues. This is considered as definite evidence for the formation of a high-spin intermediate in the latter case." @default.
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- W2015199265 date "1982-01-01" @default.
- W2015199265 modified "2023-09-25" @default.
- W2015199265 title "Kinetics of axial ligand exchange in ruthenium(II) tetraphenylporphyrin complexes" @default.
- W2015199265 doi "https://doi.org/10.1039/dt9820000095" @default.
- W2015199265 hasPublicationYear "1982" @default.
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