Matches in SemOpenAlex for { <https://semopenalex.org/work/W2015205778> ?p ?o ?g. }
Showing items 1 to 94 of
94
with 100 items per page.
- W2015205778 endingPage "1975" @default.
- W2015205778 startingPage "1972" @default.
- W2015205778 abstract "A continuous dimethylamino (CH3)2N ± (DMA) radical beam is produced in situ by the pyrolysis of dimethylnitrosamine (CH3)2NNO at 850 (0.5 ° C) in a double-heater inlet system on a double-chamber UPS machine-II which was built specifically to detect transient species. The HeI photoelectron spectrum (PES) of the (CH3)2N radical is recorded for the first time. To assign the PES bands of the (CH3)2N radical, the improved density functional theory (DFT) calculation based on the Amsterdam density functional (ADF) program package has been carried out according to C2v symmetry for the ground state of the neutral (CH3)2N radical and the equilibrium geometries of several ionic states of the cationic species. A sharp peak with the lowest ionization energy at 9.01 ± 0.02 eV comes from electron ionization of the HOMO(2b1) of the (CH3)2N radical, corresponding to the ionization of the (CH3)2N (X 2B1) to (CH3)2N+(X 1A1). The second band with vibration spacing 1980 ± 60 cm-1 comes from electron ionization of 1a2 orbital which is a strongly bound state for the (CH3)2N radical, corresponding to ionization of (CH3)2N (X 2B1) to the 3B1 state of (CH3)2N+ cation. The PES bands of the NO molecule clearly appears in the PE spectrum of the products pyrolyzed of the compound. The pyrolysis mechanism of the (CH3)2NNO compound is shown as follows:" @default.
- W2015205778 created "2016-06-24" @default.
- W2015205778 creator A5018521237 @default.
- W2015205778 creator A5058799290 @default.
- W2015205778 creator A5061835933 @default.
- W2015205778 date "1999-03-13" @default.
- W2015205778 modified "2023-10-18" @default.
- W2015205778 title "The Electronic Structure of the (CH<sub>3</sub>)<sub>2</sub>N Radical and the Pyrolysis Mechanism of Dimethylnitrosamine: A HeI Photoelectron Spectroscopic Study" @default.
- W2015205778 cites W1966054437 @default.
- W2015205778 cites W1971671866 @default.
- W2015205778 cites W1976949707 @default.
- W2015205778 cites W1982342895 @default.
- W2015205778 cites W1985954885 @default.
- W2015205778 cites W1994480324 @default.
- W2015205778 cites W2017661977 @default.
- W2015205778 cites W2020114693 @default.
- W2015205778 cites W2030687437 @default.
- W2015205778 cites W2038533471 @default.
- W2015205778 cites W2040686638 @default.
- W2015205778 cites W2041197259 @default.
- W2015205778 cites W2061266400 @default.
- W2015205778 cites W2061611328 @default.
- W2015205778 cites W2075575387 @default.
- W2015205778 cites W2086957099 @default.
- W2015205778 cites W2121213178 @default.
- W2015205778 cites W2123195204 @default.
- W2015205778 cites W3012137522 @default.
- W2015205778 doi "https://doi.org/10.1021/jp9829142" @default.
- W2015205778 hasPublicationYear "1999" @default.
- W2015205778 type Work @default.
- W2015205778 sameAs 2015205778 @default.
- W2015205778 citedByCount "16" @default.
- W2015205778 countsByYear W20152057782012 @default.
- W2015205778 crossrefType "journal-article" @default.
- W2015205778 hasAuthorship W2015205778A5018521237 @default.
- W2015205778 hasAuthorship W2015205778A5058799290 @default.
- W2015205778 hasAuthorship W2015205778A5061835933 @default.
- W2015205778 hasConcept C113196181 @default.
- W2015205778 hasConcept C121332964 @default.
- W2015205778 hasConcept C145148216 @default.
- W2015205778 hasConcept C147192597 @default.
- W2015205778 hasConcept C147597530 @default.
- W2015205778 hasConcept C152365726 @default.
- W2015205778 hasConcept C175708663 @default.
- W2015205778 hasConcept C178790620 @default.
- W2015205778 hasConcept C184779094 @default.
- W2015205778 hasConcept C185592680 @default.
- W2015205778 hasConcept C198291218 @default.
- W2015205778 hasConcept C205759337 @default.
- W2015205778 hasConcept C32909587 @default.
- W2015205778 hasConcept C36759035 @default.
- W2015205778 hasConcept C46141821 @default.
- W2015205778 hasConcept C51286037 @default.
- W2015205778 hasConcept C69523127 @default.
- W2015205778 hasConcept C96444392 @default.
- W2015205778 hasConceptScore W2015205778C113196181 @default.
- W2015205778 hasConceptScore W2015205778C121332964 @default.
- W2015205778 hasConceptScore W2015205778C145148216 @default.
- W2015205778 hasConceptScore W2015205778C147192597 @default.
- W2015205778 hasConceptScore W2015205778C147597530 @default.
- W2015205778 hasConceptScore W2015205778C152365726 @default.
- W2015205778 hasConceptScore W2015205778C175708663 @default.
- W2015205778 hasConceptScore W2015205778C178790620 @default.
- W2015205778 hasConceptScore W2015205778C184779094 @default.
- W2015205778 hasConceptScore W2015205778C185592680 @default.
- W2015205778 hasConceptScore W2015205778C198291218 @default.
- W2015205778 hasConceptScore W2015205778C205759337 @default.
- W2015205778 hasConceptScore W2015205778C32909587 @default.
- W2015205778 hasConceptScore W2015205778C36759035 @default.
- W2015205778 hasConceptScore W2015205778C46141821 @default.
- W2015205778 hasConceptScore W2015205778C51286037 @default.
- W2015205778 hasConceptScore W2015205778C69523127 @default.
- W2015205778 hasConceptScore W2015205778C96444392 @default.
- W2015205778 hasIssue "13" @default.
- W2015205778 hasLocation W20152057781 @default.
- W2015205778 hasOpenAccess W2015205778 @default.
- W2015205778 hasPrimaryLocation W20152057781 @default.
- W2015205778 hasRelatedWork W1992370907 @default.
- W2015205778 hasRelatedWork W2011751377 @default.
- W2015205778 hasRelatedWork W2023328616 @default.
- W2015205778 hasRelatedWork W2031920865 @default.
- W2015205778 hasRelatedWork W2045717026 @default.
- W2015205778 hasRelatedWork W2068738674 @default.
- W2015205778 hasRelatedWork W2084465826 @default.
- W2015205778 hasRelatedWork W2088451537 @default.
- W2015205778 hasRelatedWork W3035511436 @default.
- W2015205778 hasRelatedWork W4213305207 @default.
- W2015205778 hasVolume "103" @default.
- W2015205778 isParatext "false" @default.
- W2015205778 isRetracted "false" @default.
- W2015205778 magId "2015205778" @default.
- W2015205778 workType "article" @default.