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- W2015207625 abstract "Since mesoporous silicates (M41S) were first discovered in the early 1990s, organic–inorganic assembly combined with sol–gel processes by using surfactants as structure-directing agents had been considered to be the major pathway for creating mesoscaled periodic materials. However, unfortunately, many mesostructured materials could not be prepared by the sol–gel process. Nanocasting, using highly ordered mesoporous silica as a template, has brought forward incredible possibilities in preparing novel mesostructured materials, and has led to a great number of ordered nanowire arrays with: a) small diameter (<10 nm); b) large surface areas (up to 2500 m2 g-1) and uniform mesopores (1.5–10 nm); c) tunable 2-D or 3-D mesostructures; d) controlled morphology such as spheres, rods, films, and monoliths; and e) different components including carbon, metals, metal oxides and metal sulfides. We intend to review the results of research into replica mesostructures by nanocasting in recent years from the viewpoint of synthesis. Detailed synthetic processes are described, and problems that are often encountered in the procedure are discussed with several solutions. Many mesostructured replicas are introduced, sorted by their components, including synthetic methods, characteristics of the materials, applications and future challenges. Finally, a simple view of the prospects in this area is provided." @default.
- W2015207625 created "2016-06-24" @default.
- W2015207625 creator A5011818868 @default.
- W2015207625 creator A5024094171 @default.
- W2015207625 date "2005-01-01" @default.
- W2015207625 modified "2023-09-30" @default.
- W2015207625 title "Synthesis of replica mesostructures by the nanocasting strategy" @default.
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- W2015207625 doi "https://doi.org/10.1039/b414402c" @default.
- W2015207625 hasPublicationYear "2005" @default.
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