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- W2015209681 abstract "The abundances of C6H5+, C6H4+·, C4X4+·, and C3X3+ (X=H, D) fragments occurring in the metastable transition of benzene and perdeuterio benzene have been measured by means of electron-impact ionization. The isotope effects on the relative intensities were reproduced by the simple model calculation on the basis of the RRKM theory. The vibrational frequencies of the transition states for the deuteriated and the nondeuteriated were obtained by a vibrational analysis for the assumed geometries and force fields. The transition states for the C6H5+ and C6H4+· channels preferred a benzene structure while those for the C4H4+· and C3H3+ has a propargylcyclopropene structure. The calculated decay rates for the C6H5+, C4H4+· and C3H3+ fragmentation were compared with those of the photoion photoelectron coincidence (PIPECO) results." @default.
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- W2015209681 date "1984-02-01" @default.
- W2015209681 modified "2023-10-18" @default.
- W2015209681 title "Mass-spectral Isotope Effects in the Metastable Transition of Benzene and Perdeuterio Benzene. Model Calculation" @default.
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- W2015209681 doi "https://doi.org/10.1246/bcsj.57.452" @default.
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