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- W2015212513 abstract "A molecular field theory of the smectic-$A$$ensuremath{-}$smectic-$C$ transition has been developed for smectics with a diffused cone orientational distribution of molecules (volcano-like distribution function) in the smectic-$A$ phase and anomalously weak layer contraction in the smectic-$C$ phase. Orientational order parameters and smectic layer spacing have been calculated numerically as functions of temperature and compared with the results obtained using a model with a standard Maier-Saupe--type distribution function that has been considered before. A molecular theory of the electroclinic effect in chiral smectics has also been developed using the recently proposed simple biaxial interaction potential. A comparison has been made between the absolute values and temperature variations of the electroclinic coefficient obtained using the volcano model, the model with Maier-Saupe--type distribution, and the orthodox cone model proposed by de Vries. It has been shown that the model with a conventional ``sugar loaf'' type orientational distribution function in the smectic-$A$ phase is sufficient to describe the main properties of smectics with anomalously weak layer contraction." @default.
- W2015212513 created "2016-06-24" @default.
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- W2015212513 date "2012-02-13" @default.
- W2015212513 modified "2023-10-18" @default.
- W2015212513 title "Molecular theory of the tilting transition in smectic liquid crystals with weak layer contraction and diffused cone orientational distribution" @default.
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- W2015212513 doi "https://doi.org/10.1103/physreve.85.021701" @default.
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