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- W2015220457 abstract "Abstract Potential energy surfaces for the (HFH) 1 system that asymptotically lead to H 1 + HF( 1 Σ + ) or to H( 2 S g ) + HF + ( 2 Π)) fragments are compared over a wide range of relative geometries by using the results of ab initio calculations via the CEPA method and DIM model calculations. Recent molecular beam experiments on H + + HF suggest negligible vibrational excitation, strong rotational excitation and do not detect any charge-transfer effect. Analysis of the relative shapes of the surfaces as functions of all coordinates involved shows structural reasons for the experimental behaviour and suggests qualitative dynamical arguments for excluding the possibility of temporary charge-transfer intermediates." @default.
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- W2015220457 date "1986-09-01" @default.
- W2015220457 modified "2023-09-30" @default.
- W2015220457 title "On the possibility of charge-transfer processes in low-energy proton- HF1Σ+ collisions" @default.
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- W2015220457 doi "https://doi.org/10.1016/0009-2614(86)80232-9" @default.
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