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- W2015233191 abstract "Thiazoliumsalz-katalysierte Additionen von Aldehyden an die Vinylketone 7-12 führen zu γ-Polyketonen 5, 6, 13-28, 38-49, 4,7,10-Triketoestern 29-33 und 4,7,10-Triketonitrilen 34-37. Die Vinylketone 7-12 entstehen durch mehrfache thiazoliumsalz-katalysierte Addition und Pyrolyse von 5-Norbornen-2-carbaldehyd an Methylvinylketon, Phenylvinylketon, Acryl-säure-methylester und Acrylnitril. Addition of Aldehydes to Activated Double Bonds, XXX. — Synthesis of Unsymmetrical γ-Polyketones, 4,7,10-Trioxo Esters, and 4,7,10-Trioxo Nitriles Thiazolium salt catalyzed additions of aldehydes to the vinyl ketones 7-12 lead to γ-polyketones 5, 6, 13-28, 38-49, 4,7,10-trioxo esters 29-33, and 4,7,10-trioxo nitriles 34-37. The vinyl ketones 7-12 were obtained by repeated thiazolium salt catalyzed addition and pyrolysis of 5-norbornene-2-carbaldehyde to methyl vinyl ketone, phenyl vinyl ketone, methyl acrylate, and acrylonitrile." @default.
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- W2015233191 date "1981-09-21" @default.
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- W2015233191 title "Addition von Aldehyden an aktivierte Doppelbindungen, XXX. Synthese von unsymmetrischen γ-Polyketonen, 4,7,10-Triketoestern und 4,7,10-Triketonitrilen" @default.
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- W2015233191 doi "https://doi.org/10.1002/jlac.198119810905" @default.
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