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- W2015235320 abstract "Two conformers for the cationic rhodium(I) complexes of the title 14-membered cyclic tetrasulphides have been prepared and the conformational effect upon the nucleophilicity of rhodium(I) ion is shown by the oxidative addition reaction of CH2Cl2; {Rh[14]aneS4}Cl (1), in which the Rh atom lies 0.1332(2)Å above the plane of four S atoms, forms a dimer through a Rh ⋯ Rh [3.313(1)Å] and four Rh ···S [3.697(9)–3.822(3)Å] intermolecular non-bonded interactions as established by an X-ray crystal structure determination." @default.
- W2015235320 created "2016-06-24" @default.
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- W2015235320 date "1985-01-01" @default.
- W2015235320 modified "2023-10-17" @default.
- W2015235320 title "Cationic rhodium(<scp>I</scp>) complexes of 1,4,8,11-tetrathiacyclotetradecane ([14]aneS<sub>4</sub>) and the 6,6,13,13-tetramethyl analogue (Me<sub>4</sub>[14]aneS<sub>4</sub>). Preparation of two conformers, X-ray crystal structure of {Rh[14]aneS<sub>4</sub>}<sub>2</sub>Cl<sub>2</sub>·MeCN, and conformational effect on the nucleophilicity of the rhodium(<scp>I</scp>) ion" @default.
- W2015235320 doi "https://doi.org/10.1039/c39850001137" @default.
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