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- W2015236584 abstract "Abstract A recent synthesis of a vincadifformine (1) derivative followed a c-b-a order of bond construction,2 which postpones the introduction of the angular ethyl group until a late stage of the reaction sequence. In view of the new, ready access to compounds3,4 whose structures represent nearly the full complement of carbons characteristic of the non-tryptamine portion of the Aspidosperma alkaloids their use in the total synthesis of such natural bases could be envisaged. The present communication illustrates a c-b-a approach to Aspidosperma alkaloid synthesis by exploitation of the pyran derivative 2 and hence by early introduction of the angular ethyl group.5" @default.
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- W2015236584 date "1979-01-01" @default.
- W2015236584 modified "2023-10-17" @default.
- W2015236584 title "A Pathway of Synthesis Toward the Aspidosperma Alkaloids" @default.
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- W2015236584 doi "https://doi.org/10.1080/00397917908060954" @default.
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