FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2015256211> ?p ?o ?g. }

• W2015256211 endingPage "4880" @default.
• W2015256211 startingPage "4869" @default.
• W2015256211 abstract "A number of substituted-titanocene−alkynyl−alkenyl complexes, [(η5-C5Me4R1)2Ti(η1-C⋮CR2)(η1-(E)-CHCHR2)] (R1 = H, Me, Ph, Bz; R2 = CMe3, SiMe3, ferrocenyl; A type complexes), were obtained by reacting the corresponding bis(trimethylsilyl)ethyne complexes [(η5-C5Me4R1)2Ti(η2-Me3SiC⋮CSiMe3)] with 1-alkynes R2C⋮CH in the dark at 60 °C. The complexes undergo a coupling of the carbyl ligands upon exposure to sunlight to give titanocene complexes with 1,4-disubstituted but-1-en-3-ynes, [(η5-C5Me4R1)2Ti(3,4-η-R2C⋮CCHCHR2)] (B type complexes). In contrast to A type complexes that do not react further with an excess of tert-butylethyne and (trimethylsilyl)ethyne in the dark, B type complexes induce rapid dimerization of these terminal alkynes to 2,4-disubstituted but-1-en-3-ynes (head-to-tail dimers). This implies that the known dimerization of 1-alkynes in the presence of [(η5-C5Me4R1)2Ti(η2-Me3SiC⋮CSiMe3)] (R1 = H, Me) performed in diffuse daylight is initiated by the B type complexes originating from photoinduced conversion of the initially formed A type products. Titanocene complexes with 2,4-disubstituted but-1-en-3-ynes, [(η5-C5Me4R1)2Ti(3,4-η-R2C⋮CC(R2)CH2)] (R1 = H, Me, Ph; R2 = SiMe3), were also prepared and their participation in the catalytic cycle was demonstrated." @default.
• W2015256211 created "2016-06-24" @default.
• W2015256211 creator A5004234786 @default.
• W2015256211 creator A5012986118 @default.
• W2015256211 creator A5025144005 @default.
• W2015256211 creator A5059980683 @default.
• W2015256211 creator A5060305268 @default.
• W2015256211 creator A5061738046 @default.
• W2015256211 date "1999-10-16" @default.
• W2015256211 modified "2023-10-10" @default.
• W2015256211 title "Photoinduced Generation of Catalytic Complexes from Substituted-Titanocene−Bis(trimethylsilyl)ethyne Complexes: Contribution to the Mechanism of the Catalytic Head-to-Tail Dimerization of Terminal Alkynes" @default.
• W2015256211 cites W1970919367 @default.
• W2015256211 cites W1973692325 @default.
• W2015256211 cites W1974439978 @default.
• W2015256211 cites W1978063177 @default.
• W2015256211 cites W1983597651 @default.
• W2015256211 cites W1988239179 @default.
• W2015256211 cites W1988654106 @default.
• W2015256211 cites W1991262938 @default.
• W2015256211 cites W1995843982 @default.
• W2015256211 cites W1996830652 @default.
• W2015256211 cites W1998718476 @default.
• W2015256211 cites W2006888491 @default.
• W2015256211 cites W2008974355 @default.
• W2015256211 cites W2008981314 @default.
• W2015256211 cites W2010040570 @default.
• W2015256211 cites W2011660593 @default.
• W2015256211 cites W2014292787 @default.
• W2015256211 cites W2023742268 @default.
• W2015256211 cites W2026252627 @default.
• W2015256211 cites W2026720554 @default.
• W2015256211 cites W2027503000 @default.
• W2015256211 cites W2033440080 @default.
• W2015256211 cites W2036633036 @default.
• W2015256211 cites W2049511689 @default.
• W2015256211 cites W2056101728 @default.
• W2015256211 cites W2059383878 @default.
• W2015256211 cites W2067952673 @default.
• W2015256211 cites W2071197005 @default.
• W2015256211 cites W2076868239 @default.
• W2015256211 cites W2086287132 @default.
• W2015256211 cites W2088623222 @default.
• W2015256211 cites W2088779491 @default.
• W2015256211 cites W2090128492 @default.
• W2015256211 cites W2090933137 @default.
• W2015256211 cites W2094064501 @default.
• W2015256211 cites W2094888549 @default.
• W2015256211 cites W2095086114 @default.
• W2015256211 cites W2320392526 @default.
• W2015256211 cites W2322740401 @default.
• W2015256211 cites W234238458 @default.
• W2015256211 cites W2510000832 @default.
• W2015256211 cites W2584639363 @default.
• W2015256211 cites W2949918310 @default.
• W2015256211 cites W2950299238 @default.
• W2015256211 cites W2950340116 @default.
• W2015256211 cites W2950830093 @default.
• W2015256211 cites W2951512000 @default.
• W2015256211 cites W2953331299 @default.
• W2015256211 doi "https://doi.org/10.1021/om9905714" @default.
• W2015256211 hasPublicationYear "1999" @default.
• W2015256211 type Work @default.
• W2015256211 sameAs 2015256211 @default.
• W2015256211 citedByCount "35" @default.
• W2015256211 countsByYear W20152562112012 @default.
• W2015256211 countsByYear W20152562112013 @default.
• W2015256211 countsByYear W20152562112014 @default.
• W2015256211 countsByYear W20152562112015 @default.
• W2015256211 countsByYear W20152562112016 @default.
• W2015256211 countsByYear W20152562112017 @default.
• W2015256211 countsByYear W20152562112018 @default.
• W2015256211 countsByYear W20152562112020 @default.
• W2015256211 countsByYear W20152562112022 @default.
• W2015256211 countsByYear W20152562112023 @default.
• W2015256211 crossrefType "journal-article" @default.
• W2015256211 hasAuthorship W2015256211A5004234786 @default.
• W2015256211 hasAuthorship W2015256211A5012986118 @default.
• W2015256211 hasAuthorship W2015256211A5025144005 @default.
• W2015256211 hasAuthorship W2015256211A5059980683 @default.
• W2015256211 hasAuthorship W2015256211A5060305268 @default.
• W2015256211 hasAuthorship W2015256211A5061738046 @default.
• W2015256211 hasConcept C155647269 @default.
• W2015256211 hasConcept C161790260 @default.
• W2015256211 hasConcept C178790620 @default.
• W2015256211 hasConcept C185592680 @default.
• W2015256211 hasConcept C2777000832 @default.
• W2015256211 hasConcept C71240020 @default.
• W2015256211 hasConceptScore W2015256211C155647269 @default.
• W2015256211 hasConceptScore W2015256211C161790260 @default.
• W2015256211 hasConceptScore W2015256211C178790620 @default.
• W2015256211 hasConceptScore W2015256211C185592680 @default.
• W2015256211 hasConceptScore W2015256211C2777000832 @default.
• W2015256211 hasConceptScore W2015256211C71240020 @default.
• W2015256211 hasIssue "23" @default.
• W2015256211 hasLocation W20152562111 @default.
• W2015256211 hasOpenAccess W2015256211 @default.
• W2015256211 hasPrimaryLocation W20152562111 @default.
• W2015256211 hasRelatedWork W1531601525 @default.

• next