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• W2015256890 abstract "Hydrogen chloride is evolved at an increasing rate in the light-induced oxidation of poly(vinyl chloride) films. These accelerated kinetics were shown to result from an increased absorption of light by the polyenes formed, since the quantum yield of dehydrochlorination (ΦHCl = 0·015) is independent of the extent of the reaction in the dose range investigated. Determination of the quantum yields of the different processes involved indicate that, for each scission of the polymer backbone, 11 molecules of hydrogen chloride are evolved while three carbonyl groups, two hydroperoxides and 0·4 intermolecular crosslinks appear on the polymer chain. A mechanism that involves β-scissions of the tertiary alkoxy radicals, resulting from non-terminating interactions of α-chloro-peroxy radicals, is suggested to explain the observed increase of the polymer degradation in the presence of oxygen." @default.
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• W2015256890 date "1981-07-01" @default.
• W2015256890 modified "2023-10-12" @default.
• W2015256890 title "Photo-oxidation of poly(vinyl chloride)" @default.
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• W2015256890 doi "https://doi.org/10.1016/0144-2880(81)90021-x" @default.
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