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- W2015264552 abstract "Abstract A general synthesis of glycoconjugate α,β-ethylenic acid precursors of glycoenkephalines is described with the aim to further introduce a peptide moiety on a glucide to prepare glycoenkephalines. The Horner reaction between the lithiated dianions of 2-diethyl-phosphonoalcanoic acids and the terminal aldehyde of dialdoses lead to the expected α,β-ethylenic acids in good yields. The results are compared with those of the similar Horner reactions using the lithiated methyl 2-diethylphosphonoalcanoates as reagents. The two types of reagents are complementary, the dilithiated dianions generally lead predominantly to the E isomer whereas the lithiated monoanions derived from 2-diethylphosphonoalcanoates give mainly the Z isomer." @default.
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- W2015264552 date "1994-12-01" @default.
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- W2015264552 title "INTRODUCTION DE MOTIFS ACIDES α,β-ETHYLENIQUES EN POSITION 5 OU 6 DE PENTOSIDES ET D'HEXOSIDES PAR REACTION DE HORNER" @default.
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- W2015264552 doi "https://doi.org/10.1080/10426509408020726" @default.
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