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• W2015266811 abstract "The preparation and characterisation of fully polymeric-bound heterocycles as proton solvents is presented. Two different types of polymers are prepared: Polystyrene with imidazole terminated flexible side chains and benzimidazole covalently bonded to an inorganic SiO2 network by a flexible spacer. High proton conductivities of up to 7×10−4 S cm−1 at 200 °C have been obtained for these polymers in the absence of water. The presence of protonic charge carriers (protonated and deprotonated heterocycles) is a result of self-dissociation and the proton conductance is suggested to occur via intermolecular proton transfer and structural reorganisation within a dynamical hydrogen bond network formed by the aggregation of the terminating heterocycles." @default.
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• W2015266811 date "2003-06-01" @default.
• W2015266811 modified "2023-10-14" @default.
• W2015266811 title "New fully polymeric proton solvents with high proton mobility" @default.
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• W2015266811 doi "https://doi.org/10.1016/s0013-4686(03)00200-7" @default.
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