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- W2015266970 abstract "Solvothermal reaction of [MnCl2(terpy)] with elemental As and Se at a 1:1:2 molar ratio in H2O/trien (10:1) at 150 °C affords the linear trimanganese(II) complex [{Mn(terpy)}3(μ-AsSe4)2] (1). The tridentate [AsSe2(Se2)]3− anions of 1 chelate the terminal {Mn(terpy)}2+ fragments and bridge these through their remaining Se atom to the central {Mn(terpy)}2+ moiety. Weak interactions of Mn1···Se and Mn3···Se bonds with length 2.914(7) and 3.000(7) A link the molecules of 1 into infinite chains. Treatment of [MnCl2(cyclam)]Cl with As and Se at a 1:1:2 molar ratio in superheated H2O/CH3OH (1:1) at 150 °C yields the dinuclear complex [{Mn(cyclam)}2 (μ-As2Se6)] (2), whose novel [(AsSe2)2(μ-Se2)]4− ligands bridge the MnII atoms in a μ-1κ2Se1, Se2: 2κ2Se5,Se6 manner." @default.
- W2015266970 created "2016-06-24" @default.
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- W2015266970 date "2009-04-21" @default.
- W2015266970 modified "2023-09-26" @default.
- W2015266970 title "ChemInform Abstract: Manganese(II) Complexes with Bridging Selenidoarsenate(III) Anions [AsSe2(Se2)]3-and [(AsSe2)2(μ-Se2)]4-." @default.
- W2015266970 cites W2950408465 @default.
- W2015266970 doi "https://doi.org/10.1002/chin.200916019" @default.
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