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• W2015271699 abstract "The influence of the ratio of the rod radius, r, to field radius, r(0), on the peak shape for a linear quadrupole mass filter constructed with round rods has been investigated. The expansion of the potential in multipoles, phi(N),Phi(x, y) = sum(infinity)(N=0)A(N)phi(N)/r(N)(0) has been considered, and the peak shape and resolution have been determined by numerical calculation of ion trajectories in quadrupoles with different ratios, r/r(0). Geometries that make the dodecapole term (A(6)) zero (r/r(0) = 1.14511) do not give the best performance because the contribution of the 20-pole term, A(10), must be considered. The optimum ratio is r/r(0) approximately 1.13. With this ratio the dodecapole term (A(6)) is ca. 1 x 10(-3), but its effects are partially compensated by the A(10) term which has similar magnitude, but opposite sign." @default.
• W2015271699 created "2016-06-24" @default.
• W2015271699 creator A5007968234 @default.
• W2015271699 creator A5073987688 @default.
• W2015271699 date "2002-06-24" @default.
• W2015271699 modified "2023-10-09" @default.
• W2015271699 title "Influence of the 6th and 10th spatial harmonics on the peak shape of a quadrupole mass filter with round rods" @default.
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• W2015271699 doi "https://doi.org/10.1002/rcm.735" @default.
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