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- W2015273668 abstract "A synthesis of the keto-triol formyl enamine moiety (3) in the marine metabolite halichondramide (1) is described. The synthesis features judicious applications of the Evans chiral aldol protocol in combination with the controlled ring opening of chiral α-epoxy alcohol precursor molecules to elaborate the units (5) and (6). A Wadsworth-Emmons coupling between (5) and (6) next provided (18), which was then elaborated to (3) via the key intermediates (19) and (21)." @default.
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- W2015273668 title "Synthetic studies towards halichondramides, and related novel tris-oxazole containing macrolides from marine organisms. A concise route to the keto-triol formyl enamine moiety." @default.
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- W2015273668 doi "https://doi.org/10.1016/s0040-4039(00)79858-3" @default.
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