Matches in SemOpenAlex for { <https://semopenalex.org/work/W2015276617> ?p ?o ?g. }
- W2015276617 endingPage "123" @default.
- W2015276617 startingPage "117" @default.
- W2015276617 abstract "When two benzene rings are fused to a tetraaryl-o-quinodimethane skeleton, sterically hindered helical molecules 1 acquire a high thermodynamic stability. Because the tetraarylbutadiene subunit contains electron-donating alkoxy groups, 1 undergo reversible two-electron oxidation to 22+, which can be isolated as deeply colored stable salts. Intramolecular transfer of the point chirality (e.g., sec-butyl) on the aryl groups to helicity induces a diastereomeric preference in dications 2 b2+ and 2 c2+, which represents an efficient method for enhancing circular-dichroism signals. Thus, those redox pairs can serve as new electrochiroptical response systems. X-ray analysis of dication 22+ revealed π–π stacking interaction of the diarylmethylium moieties, which is also present in solution. The stacking geometry is the key contributor to the chirosolvatochromic response." @default.
- W2015276617 created "2016-06-24" @default.
- W2015276617 creator A5005859169 @default.
- W2015276617 creator A5012934537 @default.
- W2015276617 creator A5022223697 @default.
- W2015276617 creator A5037908115 @default.
- W2015276617 creator A5040801081 @default.
- W2015276617 creator A5043346174 @default.
- W2015276617 creator A5048014569 @default.
- W2015276617 creator A5054938294 @default.
- W2015276617 creator A5073533097 @default.
- W2015276617 creator A5084976321 @default.
- W2015276617 date "2012-11-21" @default.
- W2015276617 modified "2023-09-25" @default.
- W2015276617 title "7,7,8,8-Tetraaryl-<i>o</i>-quinodimethane Stabilized by Dibenzo Annulation: A Helical π-Electron System That Exhibits Electrochromic and Unique Chiroptical Properties" @default.
- W2015276617 cites W1964002061 @default.
- W2015276617 cites W1966211483 @default.
- W2015276617 cites W1969885133 @default.
- W2015276617 cites W1976972411 @default.
- W2015276617 cites W1978148871 @default.
- W2015276617 cites W1985587620 @default.
- W2015276617 cites W1992877466 @default.
- W2015276617 cites W2000000558 @default.
- W2015276617 cites W2005472051 @default.
- W2015276617 cites W2009372076 @default.
- W2015276617 cites W2011150528 @default.
- W2015276617 cites W2011393994 @default.
- W2015276617 cites W2032003798 @default.
- W2015276617 cites W2039135847 @default.
- W2015276617 cites W2058829566 @default.
- W2015276617 cites W2070169824 @default.
- W2015276617 cites W2077317174 @default.
- W2015276617 cites W2081719428 @default.
- W2015276617 cites W2083968815 @default.
- W2015276617 cites W2089658450 @default.
- W2015276617 cites W2089752558 @default.
- W2015276617 cites W2092385424 @default.
- W2015276617 cites W2102047585 @default.
- W2015276617 cites W2103799777 @default.
- W2015276617 cites W2106433565 @default.
- W2015276617 cites W2109838869 @default.
- W2015276617 cites W2118011826 @default.
- W2015276617 cites W2120721552 @default.
- W2015276617 cites W2123109524 @default.
- W2015276617 cites W2123436738 @default.
- W2015276617 cites W2143660074 @default.
- W2015276617 cites W2157443012 @default.
- W2015276617 cites W2950732046 @default.
- W2015276617 cites W2950816840 @default.
- W2015276617 cites W2951185719 @default.
- W2015276617 cites W2952007741 @default.
- W2015276617 cites W4235388061 @default.
- W2015276617 cites W4236457229 @default.
- W2015276617 cites W4248753675 @default.
- W2015276617 cites W4250408335 @default.
- W2015276617 cites W4254140952 @default.
- W2015276617 cites W4254962725 @default.
- W2015276617 cites W4323284561 @default.
- W2015276617 cites W568489663 @default.
- W2015276617 cites W2057751748 @default.
- W2015276617 doi "https://doi.org/10.1002/chem.201203092" @default.
- W2015276617 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23169568" @default.
- W2015276617 hasPublicationYear "2012" @default.
- W2015276617 type Work @default.
- W2015276617 sameAs 2015276617 @default.
- W2015276617 citedByCount "25" @default.
- W2015276617 countsByYear W20152766172013 @default.
- W2015276617 countsByYear W20152766172014 @default.
- W2015276617 countsByYear W20152766172015 @default.
- W2015276617 countsByYear W20152766172016 @default.
- W2015276617 countsByYear W20152766172017 @default.
- W2015276617 countsByYear W20152766172018 @default.
- W2015276617 countsByYear W20152766172019 @default.
- W2015276617 countsByYear W20152766172020 @default.
- W2015276617 countsByYear W20152766172021 @default.
- W2015276617 crossrefType "journal-article" @default.
- W2015276617 hasAuthorship W2015276617A5005859169 @default.
- W2015276617 hasAuthorship W2015276617A5012934537 @default.
- W2015276617 hasAuthorship W2015276617A5022223697 @default.
- W2015276617 hasAuthorship W2015276617A5037908115 @default.
- W2015276617 hasAuthorship W2015276617A5040801081 @default.
- W2015276617 hasAuthorship W2015276617A5043346174 @default.
- W2015276617 hasAuthorship W2015276617A5048014569 @default.
- W2015276617 hasAuthorship W2015276617A5054938294 @default.
- W2015276617 hasAuthorship W2015276617A5073533097 @default.
- W2015276617 hasAuthorship W2015276617A5084976321 @default.
- W2015276617 hasConcept C101643646 @default.
- W2015276617 hasConcept C121332964 @default.
- W2015276617 hasConcept C123669783 @default.
- W2015276617 hasConcept C124668440 @default.
- W2015276617 hasConcept C133571119 @default.
- W2015276617 hasConcept C138716334 @default.
- W2015276617 hasConcept C147789679 @default.
- W2015276617 hasConcept C161790260 @default.
- W2015276617 hasConcept C17525397 @default.
- W2015276617 hasConcept C178790620 @default.
- W2015276617 hasConcept C185592680 @default.
- W2015276617 hasConcept C201194858 @default.