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- W2015278528 abstract "Reaction of [WI(CO)2(η-C7H7)] with Ag[BF4] in acetonitrile yields the trihaptocycloheptatrienyl complex [W(CO)2(NCCH3)3(η3-C7H7)][BF4] which affords [W(CO)2(NCCH3)(η-C7H7)][BF4] (1a) on stirring in CH2Cl2. A similar reaction sequence is observed starting from [MoI(CO)2(η-C7H7)] but a mixture of [Mo(CO)2(NCCH3)3(η3-C7H7)][BF4] (2b) and [Mo(CO)2(NCCH3)(η-C7H7)][BF4] (1b) is formed in CH3CN. Treatment of [M(CO)2(NCCH3)(η-C7H7)]+ (M = Mo, W) with Li[M(CO)3(η-C5R5)] (M = Mo, R = H or Me; M = W,R = H) affords asymmetric homobinuclear complexes [M(CO)3(η-C5R5)M(CO)2(η-C7H7)] (4). Ultraviolet irradiation of [Mo(CO)2(NCCH3)(η-C7H7)][BF4] in CH3CN forms [Mo(CO)(NCCH3)2(η-C7H7)][BF4] (5) whilst irradiation of [Cr(CO)3(η-C7H7)][PF6] in CH3CN followed by addition of P(OMe)3 gives [Cr(CO){P(OMe)3}2(η-C7H7)][PF6]." @default.
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- W2015278528 date "1987-06-01" @default.
- W2015278528 modified "2023-10-16" @default.
- W2015278528 title "The formation and synthetic applications of new acetonitrile derivatives of cycloheptatrienyl-molybdenum and -tungsten complexes; synthesis of binuclear [M(CO)3(η-C5R5)M(CO)2(η-C7H7)] (M = Mo, R = H or Me; M = W, R = H)" @default.
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- W2015278528 doi "https://doi.org/10.1016/0022-328x(87)80213-9" @default.
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