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- W2015289360 abstract "The structure and the behavior of decomposition of the carbonaceous solid which was formed on the surface of molecular sieve 5A by electron beam irradiation of methane at 300°C have been studied by Auger electron spectroscopy and X-ray powder diffraction, and have been examined using volatile product analyses during electron impact under an H2 atmosphere and during H+2 ion bombardment on the solid using a quadrupole mass filter. The carbon KLL Auger spectrum of the solid is similar to that of amorphous/graphitic carbon. The X-ray diffraction pattern of the solid did not give the diffraction peak corresponding to the interlayer spacing of the graphite crystal structure, indicating that the solid has an amorphous carbon structure. Both electron impact under an H2 atmosphere and H+2 ion bombardment on the solid near 50°C produced hydrocarbons such as methane and ethane, the yields of which all increased with increasing impact temperature, and raising the impact temperature to 200°C resulted in the formation of ethylene and propylene together with methane, ethane and propane. These results are compared with the results for graphite, and also are discussed in connection with the results obtained by the hydrogenolysis of a carbonaceous solid under electron beam irradiation." @default.
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- W2015289360 date "1988-05-01" @default.
- W2015289360 modified "2023-09-25" @default.
- W2015289360 title "Structure and decomposition of the carbonaceous solid produced on the surface of molecular sieve 5A by irradiation of methane" @default.
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- W2015289360 doi "https://doi.org/10.1016/0169-4332(88)90001-3" @default.
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