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- W2015296007 abstract "The use of the solution redox species, [Os(bpy)2Cl2]+/0, [Os(bpy)2(MeIm)Cl]2+/+ and [Fe(CN)6]4−/3−, where bpy is 2,2-bipyridine and MeIm is N-methylimidazole, as electron mediators in the enzymatic reduction of oxygen by tyrosinase is investigated. Co-immobilization of both enzyme and an osmium redox mediator in a hydrogel on glassy carbon electrodes results in a biosensor for the ‘reagentless’ addressing of enzyme activity, consuming only oxygen present in solution. Immobilized enzyme inhibition biosensors can thus be constructed for the detection of tyrosinase inhibitors, such as sodium azide, using this approach. The enzyme inhibition biosensor can detect levels of azide as low as 5 × 10−6 mol dm−3 in solution and may be useful in environmental monitoring applications and as an early warning poison sensor." @default.
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- W2015296007 date "1995-10-01" @default.
- W2015296007 modified "2023-10-06" @default.
- W2015296007 title "Electrically ‘wired’ tyrosinase enzyme inhibition electrode for the detection of respiratory poisons" @default.
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- W2015296007 doi "https://doi.org/10.1002/elan.1140071008" @default.
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