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- W2015304051 abstract "The photo-chemical behaviour of a number of mono- and polyfunctional commercial phenolic antioxidants has been examined using kinetic micro-second flash photolysis. The technique provides useful information on the relationship between antioxidant structure and the efficiency of phenoxy radical production. The kinetics of decay of the phenoxy radicals are also found to be dependent on structure. Mono-functional antioxidants give phenoxy radicals which decay by a second-order process whereas polyfunctional antioxidants give phenoxy radicals that decay by a first-order process. In the former case dimerisation to give bisphenolic coupling products is observed whereas, with the latter, this process is sterically inhibited. The value of flash photolysis as a probe for studying antioxidant activity is discussed." @default.
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- W2015304051 date "1983-01-01" @default.
- W2015304051 modified "2023-10-18" @default.
- W2015304051 title "Flash photolysis and antioxidant activity" @default.
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- W2015304051 doi "https://doi.org/10.1016/0141-3910(83)90023-x" @default.
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