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- W2015304844 abstract "Abstract Micropore size distributions of Cs2.1H0.9PW12O40 and 0.5 wt% Pt-Cs2.1H0.9PW12O40 as well as H-ZSM-5, H-Y and AlPO4-5 as standard porous materials were analyzed by Ar porosimetry, assuming cylindrical pores consisting of oxide ions. The calculated pore-widths of H-ZSM-5, HY and AlPO4-5 were in agreement with the pore-opening sizes determined by XRD. The Ar porosimetry demonstrated that Cs2.1H0.9PW12O40 and 0.5 wt% Pt-Cs2.1H0.9PW12O40 possess only ultramicropores having widths of about 0.5 nm. Adsorption of various molecules revealed that the pore widths of these heteropoly compounds were in the range 0.43–0.59 nm, which is consistent with the results of the Ar porosimetry. In conclusion, nearly uniformly sized micropores are formed on both Cs2.1H0.9PW12O40 and 0.5 wt% Pt-Cs2.1H0.9PW12O40." @default.
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- W2015304844 date "1998-12-01" @default.
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- W2015304844 title "Micropore size distribution by argon porosimetry for cesium hydrogen salts of 12-tungstophosphoric acid" @default.
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- W2015304844 doi "https://doi.org/10.1016/s1387-1811(98)00221-2" @default.
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