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- W2015319310 abstract "A series of compounds, (η5-C5H4C4H9)2Mo2(CO)4(μ-η2:2-acetylene), where acetylene=3-hexyne, diphenylacetylene, phenylacetylene and 1-phenylpropyne, was prepared and characterized by IR, 1H- and 13C-NMR spectroscopies and MS. Photolysis of these compounds was carried out in frozen Nujol at 77 K. IR spectra established the presence of two isomeric carbonyl-loss species, (η5-C5H4C4H9)2Mo2(CO)2(μ-η1,η2-CO)(μ-η2:2-acetylene), A, and (η5-C5H4C4H9)2Mo2(μ-CO)3(μ-η2:2-acetylene), B. A is formed by photolysis into low energy electronic transitions associated with the tetrahedrane core of the parent molecule, while B is formed by either photolysis into electronic bands associated with A, or photolysis into the high energy charge-transfer bands of the parent molecule. These photointermediates are likely to be involved in the formation of ‘fly-over’ compounds, resulting from thermally or photochemically induced multiple substitution of acetylenes." @default.
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- W2015319310 date "1998-06-01" @default.
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- W2015319310 title "Photolysis of (η5-C5H4C4H9)2Mo2(CO)4(μ-η2:2-RCCR′) in frozen Nujol matrices" @default.
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- W2015319310 doi "https://doi.org/10.1016/s0022-328x(98)00512-9" @default.
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